What kind of solids are soluble in liquid mercury
In its inorganic form, mercury occurs abundantly in the environment, primarily as the minerals cinnabar and metacinnabar, and as impurities in other minerals. Mercury can readily combine with chlorine, sulfur, and other elements, and subsequently weather to form inorganic salts.
Inorganic mercury salts can be transported in water and occur in soil. Dust containing these salts can enter the air from mining deposits of ores that contain mercury. Emissions of both elemental or inorganic mercury can occur from coal-fired power plants, burning of municipal and medical waste, and from factories that use mercury. Inorganic mercury can also enter water or soil from the weathering of rocks that contain inorganic mercury salts, and from factories or water treatment facilities that release water contaminated with mercury.
Although the use of mercury salts in consumer products, such as medicinal products, have been discontinued, inorganic mercury compounds are still being widely used in skin lightening soaps and creams. Mercuric chloride is used in photography and as a topical antiseptic and disinfectant, wood preservative, and fungicide. In the past, mercurous chloride was widely used in medicinal products, including laxatives, worming medications, and teething powders.
It has since been replaced by safer and more effective agents. Mercuric sulfide is used to color paints and is one of the red coloring agents used in tattoo dyes.
Human exposure to inorganic mercury salts can occur both in occupational and environmental settings. Occupations with higher risk of exposure to mercury and its salts include mining, electrical equipment manufacturing, and chemical and metal processing in which mercury is used. In the general population, exposure to mercuric chloride can occur through the dermal route from the use of soaps and creams or topical antiseptics and disinfectants. Another, less well-documented, source of exposure to inorganic mercury salts among the general population is from their use in ethnic religious, magical, and ritualistic practices and in herbal remedies.
When inorganic mercury salts can become attached to airborne particles. Rain and snow deposit these particles on land. Even after mercury gets deposited on land, it often returns to the atmosphere, as a gas or associated with particles, and then redeposits elsewhere. As it cycles between the atmosphere, land, and water, mercury undergoes a series of complex chemical and physical transformations, many of which are not completely understood. Microscopic organisms can combine mercury with carbon, thus converting it from an inorganic to organic form.
Methylmercury is the most common organic mercury compound found in the environment, and is highly toxic. Learn about how people are most often exposed to methylmercury and about the adverse health effects that exposures to methylmercury can produce.
The focus of "Chapter Water" was water's role in the formation of aqueous solutions. We examined the primary characteristics of a solution and how water is able to dissolve solid solutes; we differentiated between a solution, a suspension, and a colloid. There are many examples of solutions that do not involve water at all, or that involve solutes that are not solids. The table below summarizes the possible combinations of solute-solvent states, along with examples of each.
Our air is a homogenous mixture of many different gases and therefore qualifies as a solution. Some mercury salts such as HgCl 2 are sufficiently volatile to exist as an atmospheric gas. However, the water solubility and chemical reactivity of these inorganic or divalent mercury gases lead to much more rapid deposition from the atmosphere than for elemental mercury.
This results in significantly shorter atmospheric lifetimes for these divalent mercury gases than for the elemental mercury gas. When mercury combines with carbon, the compounds formed are called "organic" mercury compounds or organomercurials.
There is a potentially large number of organic mercury compounds such as dimethylmercury , phenylmercury , ethylmercury and methylmercury ; however, by far the most common organic mercury compound in the environment is methylmercury. Like the inorganic mercuric compounds , both methylmercury and phenylmercury exist as "salts" for example, methylmercuric chloride or phenylmercuric acetate. When pure, most forms of methylmercury and phenylmercury are white crystalline solids.
Dimethylmercury, however, is a colourless liquid. Several forms of mercury occur naturally in the environment. The most common natural forms of mercury found in the environment are metallic mercury , mercuric sulphide, mercuric chloride, and methylmercury. Some micro-organisms and natural processes can change the mercury in the environment from one form to another. Elemental mercury in the atmosphere can undergo transformation into inorganic mercury forms, providing a significant pathway for deposition of emitted elemental mercury.
The most common organic mercury compound that micro-organisms and natural processes generate from other forms is methylmercury. Methylmercury is of particular concern because it can build up bioaccumulate and biomagnify in many edible freshwater and saltwater fish and marine mammals to levels that are many thousands of times greater than levels in the surrounding water.
Being an element, mercury cannot be broken down or degraded into harmless substances. Mercury may change between different states and species in its cycle, but its simplest form is elemental mercury , which itself is harmful to humans and the environment. The different forms mercury exists in such as elemental mercury vapour, methylmercury or mercuric chloride are commonly designated "species".
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